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Projects: Projects for Investigator
Reference Number EP/P019919/1
Title Charging ahead with Multi-layer Ceramic Capacitor materials
Status Completed
Energy Categories Nuclear Fission and Fusion(Nuclear Fission, Nuclear supporting technologies) 2%;
Not Energy Related 94%;
Other Power and Storage Technologies(Electric power conversion) 2%;
Hydrogen and Fuel Cells(Fuel Cells) 2%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Metallurgy and Materials) 50%;
ENGINEERING AND TECHNOLOGY (Electrical and Electronic Engineering) 50%;
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Dr JS Dean
No email address given
Engineering Materials
University of Sheffield
Award Type Standard
Funding Source EPSRC
Start Date 01 July 2017
End Date 30 September 2018
Duration 15 months
Total Grant Value £99,802
Industrial Sectors No relevance to Underpinning Sectors
Region Yorkshire & Humberside
Programme NC : Engineering, NC : Physical Sciences
 
Investigators Principal Investigator Dr JS Dean , Engineering Materials, University of Sheffield (100.000%)
  Industrial Collaborator Project Contact , AVX Corporation Coleraine Plant (0.000%)
Web Site
Objectives
Abstract Multi-layered ceramic capacitors (MLCCs) are the foundation of the electronics (passive components) industry. Each layer within a MLCC is made by sintering a powdered, typically a chemically-doped, functional oxide such as Barium Titanate. This processing route generates a complex microstructure that can include grains, grain-boundaries, pores, interface roughness and graded material properties. Many of these microstructural effects are known to influence device performance but the knowledge of their exact mechanism and strength of their effect is limited. At present the favoured approach towards optimising these effects is based on trial and error experimentation; however, this is challenging and time and resource consuming. It would benefit both academics and industry working on MLCC systems to be able to analyse such microstructural phenomena in a resource efficient, controlled and systematic way. This would not only allow a faster route towards optimisation of current materials and devices, but also allow quickly the analysis of rare earth-free sustainable alternatives.To achieve this, the project will develop new capabilities in modelling functional materials. We shall develop an advanced microstructural package to create realistic three-dimensional microstructures representing the main microstructural features listed above. By combining this with a state-of-the-art finite element modelling package, we shall be able to test what effects these have on device performance and allow us to guide the processing of the underlaying materials. While this proposal will be targeted towards challenges in functional oxide materials for MLCCs, due to the flexibility of the methodologies used, the codes will also be applicable to a much wider range of functional materials and devices. This includes but is not limited to solid oxide fuel cells, thermoelectric generators, piezo-electric sensors & actuators and beyond into magnetic and radiation damaged materials.The microstructural generation package will be based on two sources. Firstly, systems will be created from the analysis of experimental microstructures supplied by experimental groups and our industrial partner (AvX Ltd). Secondly, artificial systems will be generated using an array of mathematical algorithms, allowing controllable characteristics and a systematic approach in analysis. The first study using this new package will be to better understand how the doping of the ceramic material, that forms the physical 'core-shell' microstructure, can influence the current flow through the microstructure. This will be extended to how inadequate mixing of the dopants into the base material can manifest itself in a poor electrical response and performance of the device. Further analysis will be conducted on the effects of porosity and interfacial ceramic/metal electrode roughness that contribute to advancing degradation in in MLCCs and are ultimately considered to be the limiting factors in devicelifetime.
Publications (none)
Final Report (none)
Added to Database 14/08/17